METAL ALKOXIDES - MODELS FOR METAL-OXIDES .4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES - W2(MU-C2H2)REVERSIBLE2W=CH

被引：124

作者：

CHISHOLM, MH ^{[1
]}

FOLTING, K ^{[1
]}

HOFFMAN, DM ^{[1
]}

HUFFMAN, JC ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1984年 / 106卷 / 22期

关键词：

D O I：

10.1021/ja00334a055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：6794 / 6805

页数：12

共 32 条

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[5]

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[9] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES - AN ALTERNATIVE TO THE METATHESIS REACTION M=M+-C=C--]2M=C [J].

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[10] REACTIONS OF METAL-TO-METAL MULTIPLE BONDS .6. REVERSIBLE CARBONYLATION OF HEXAKIS(TERT-BUTOXY)DIMOLYBDENUM (M=M) - CARBONYL-BRIDGED METAL-TO-METAL DOUBLE-BOND, MO2(OBU-T)6(CO) (M=M) [J].

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