CHIRAL AMINAL TEMPLATES .4. CHIRAL ARYL METALLIC REAGENTS - REACTIONS WITH ALDEHYDES

被引：25

作者：

COMMERCON, M ^{[1
]}

MANGENEY, P ^{[1
]}

TEJERO, T ^{[1
]}

ALEXAKIS, A ^{[1
]}

机构：

[1] UNIV P&M CURIE,CHIM ORGANOELEMENTS LAB,CNRS,URA 856,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1990年 / 1卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)86315-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral aryl metallic derivatives are generated from chiral o-bromo imidazolidines or acetals, prepared from chiral diols or diamines having a C2 axis of symmetry. These reagents react with aldehydes with moderate to high diastereoselectivities. Removal of the chiral auxiliary, then leads to homochiral lactols 7. © 1990.

引用

页码：287 / 290

页数：4

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