EXPERIMENTS DIRECTED TOWARDS THE SYNTHESIS OF ANTHRACYCLINONES .26. THE PREPARATION OF CHIRAL INTERMEDIATES FOR ANTHRACYCLINONE SYNTHESIS

被引：5

作者：

BEAUREGARD, DA ^{[1
]}

CAMBIE, RC ^{[1
]}

DANSTED, PC ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 03期

关键词：

D O I：

10.1071/CH9950669

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(2'R)-1,5-Dimethoxy-2(2'-methyloxiran-2'-y (8), an intermediate for the synthesis of fridamycin E, has been prepared enantioselectively via the diol (15). The diol (15) was prepared in high yield by asymmetric cis-hydroxylation of the alkene (11). The analogous diol (22), a vineomycinone B-2 precursor, was also prepared.

引用

页码：669 / 676

页数：8

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