ISOLATION AND X-RAY STRUCTURES OF THE HEXAMETHYLPHOSPHORAMIDE (HMPA)-COORDINATED LANTHANIDE(II) DIIODIDE COMPLEXES [SMI(2)(HMPA)(4)] AND [YB(HMPA)(4)(THF)(2)]I-2

被引：104

作者：

HOU, ZM

WAKATSUKI, Y

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 10期

关键词：

D O I：

10.1039/c39940001205

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of samarium diiodide (SmI2) with hexamethylphosphoramide (hmpa) in tetrahydrofuran (thf) gave [SmI2(hmpa)(4)] 1 after recrystallization from toluene, while in the case of YbI2, crystals of [Yb(hmpa)(4)(thf)(2)]I-2 2 were obtained from thf; both 1 and 2 have been structurally characterized and;the influence of hmpa on the reactivity of SmI2 is discussed.

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页码：1205 / 1206

页数：2

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