CONTROL OF THE MANGANESE-OXYGEN REACTION IN PURE IRON MELTS

被引:24
作者
DIMITROV, S [1 ]
WEYL, A [1 ]
JANKE, D [1 ]
机构
[1] MAX PLANCK INST EISENFORSCH GMBH,W-4000 DUSSELDORF,GERMANY
来源
STEEL RESEARCH | 1995年 / 66卷 / 03期
关键词
D O I
10.1002/srin.199501092
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
EMF sensor measurements using ZrO2(CaO) or ThO2(Y2O3) plug-type sensors with a Cr-Cr2O3 reference were performed to redetermine the Mn-O equilibrium reaction. In these experiments a strong effect of deoxidation of manganese was ascertained at saturation with solid deoxidation products. The measuring interval of the sensors at MnO saturation was invited to about 12 min due to chemical corrosion of the used Al2O3 sheaths. In the case of double saturation with solid MnO . Al2O3 (A) the sensors could be used as long as desirable. Moreover, the combined deoxidation of the iron melt with Mn and Al was investigated. An auxiliary electrode at the tip of the sensor ensured rapid saturation of the iron melt with solid MnO or MnO . Al2O3 + Al2O3.
引用
收藏
页码:87 / 92
页数:6
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