O-H ... PI(ARENE) INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURE OF 1,1,2-TRIPHENYLETHANOL

被引：31

作者：

FERGUSON, G ^{[1
]}

GALLAGHER, JF ^{[1
]}

GLIDEWELL, C ^{[1
]}

ZAKARIA, CM ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193007164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,1,2-triphenylethanol molecule, Ph2(PhCH2)COH (1), forms centrosymmetric dimers in the solid state. The shortest O ... O separation, 5.837 (3) angstrom, is too long for any O-H ... O hydrogen-bond formation. Instead, there are O-H ... pi(arene) interactions between the hydroxyl group of one molecule and a phenyl group of a centrosymmetrically related molecule. The O ... C and H ... C distances between the hydroxyl group and the closest phenyl-ring C atom are 3.525 (4) and 2.73 (4) angstrom, respectively. These intermolecular contacts are the only driving force towards dimer formation in the solid state.

引用

页码：70 / 73

页数：4

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