DIRECT ESTERIFICATION OF PHOSPHATES WITH VARIOUS HALIDES AND ITS APPLICATION TO SYNTHESIS OF CAMP ALKYL TRIESTERS

被引：22

作者：

FURUTA, T ^{[1
]}

TORIGAI, H ^{[1
]}

OSAWA, T ^{[1
]}

IWAMURA, M ^{[1
]}

机构：

[1] TOHO UNIV,FAC SCI,DEPT BIOMOLEC SCI,2-2-1 MIYAMA,FUNABASHI,CHIBA 274,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 24期

关键词：

D O I：

10.1039/p19930003139

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Esterification of phosphates with various halides, including acid chlorides, phosphoryl trichloride and tin chloride, was achieved in 57-99% isolated yield using silver(I) oxide. The reaction was successfully applied to the preparation of phosphate triesters sensitive to acids and bases. cAMP benzyl esters were also prepared by this method.

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页码：3139 / 3142

页数：4

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