SYNTHESIS AND CHARACTERIZATION OF A NEW MONOMER WITH PENDANT HINDERED AMINE GROUP

被引:12
|
作者
LEE, CS
LAU, WWY
LEE, SY
GOH, SH
机构
[1] NATL UNIV SINGAPORE,DEPT CHEM ENGN,SINGAPORE 0511,SINGAPORE
[2] NATL UNIV SINGAPORE,DEPT CHEM,SINGAPORE 0511,SINGAPORE
关键词
PIPERIDINYL CARBAMATE; HALS; SYNTHESIS; CHARACTERIZATION;
D O I
10.1002/pola.1991.080291307
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A new monomer, 1,2,2,6,6-pentamethyl-4-piperidinyl m-isopropenyl-alpha,alpha-dimethylbenzyl carbamate, was synthesized by direct addition of 1,2,2,6,6-pentamethyl-4-piperidinol to m-isopropenyl-alpha,alpha-dimethylbenzyl isocyanate in the presence of dibutyltin dilaurate catalyst at elevated temperatures. It was characterized by FT-IR, H-1-NMR, MS, and elemental analysis. It is a potential hindered amine light stabilizer as it contains the 2,2,6,6-tetraalkylpiperidine moiety and its vinylic functionality makes it polymerizable.
引用
收藏
页码:1889 / 1893
页数:5
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