ENZYME CATALYZED MONOHYDROLYSIS OF 2-ARYL-1,3-PROPANEDIOL DIACETATES - A STUDY OF STRUCTURAL EFFECTS OF THE ARYL MOIETY ON THE ENANTIOSELECTIVITY

被引：59
作者：
GUANTI, G
NARISANO, E
PODGORSKI, T
THEA, S
WILLIAMS, A
机构：
[1] CNR,CTR STUDIO DIARILOIDI,I-16132 GENOA,ITALY
[2] UNIV KENT,CHEM LABS,CANTERBURY CT2 7NH,KENT,ENGLAND
来源：
TETRAHEDRON | 1990年 / 46卷 / 20期
关键词：
D O I：
10.1016/S0040-4020(01)87892-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
PPL catalyzed monohydrolysis of 2-aryl substituted 13-propanediol diacetates afforded the corresponding monoacetates in acceptable to fair chemical and optical yields. Electronic effects in the aromatic ring were examined. Elaboration of some 2-arylpropanediol monoacetates to optically active 2-arylpropanols and propanoic acids was performed. © 1990.
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页码：7081 / 7092
页数：12
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