PALLADIUM-CATALYZED VINYLATION OF ALLYLIC ALCOHOLS WITH ENOL TRIFLATES - A CONVENIENT SYNTHESIS OF CONJUGATED DIENOLS

被引：64

作者：

BERNOCCHI, E

CACCHI, S

CIATTINI, PG

MORERA, E

ORTAR, G

机构：

[1] UNIV ROME LA SAPIENZA,DIPARTIMENTO STUDI CHIM & TECNOL SOSTANZE BIOL ATTIVE,I-00185 ROME,ITALY

[2] UNIV ROME LA SAPIENZA,DIPARTIMENTO FARMACEUTICI,I-00185 ROME,ITALY

[3] UNIV ROME LA SAPIENZA,CNR,CTR STUDIO CHIM FARM,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)79603-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Heck-type reactions involving enol triflates 1 and allylic alcohols 2 result in the formation of conjugated dienols as the major products. The regioselectivity for substitution at the terminal carbon of the alcohol is generally good and dienols 3 can be isolated in synthetically useful yields.

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页码：3073 / 3076

页数：4

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