REGIOSPECIFIC SYNTHESIS OF POLYSUBSTITUTED NAPHTHALENES AND IODOACYLNAPHTHOQUINONES VIA ZIRCONOCENE COMPLEXES OF NAPHTHALYNES

被引：41

作者：

BUCHWALD, SL

KING, SM

机构：

[1] Department of Chemistry, Massachusetts Institute of Technology, Cambridge

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 01期

关键词：

D O I：

10.1021/ja00001a037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zirconocene complexes of substituted naphthalynes have been generated in situ and trapped with nitriles to form azametallacycles with excellent regiochemical control. These compounds can be converted into ketones, alpha-iodo ketones, and iodoacylnaphthoquinones with experimentally simple procedures.

引用

页码：258 / 265

页数：8

共 30 条

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