SYNTHESIS OF AN OPTICALLY ACTIVE 13-BETA-METHYL 14-BETA-HYDROXY STEROID VIA BASE-CATALYZED REACTIONS

被引：31

作者：

RUEL, R ^{[1
]}

DESLONGCHAMPS, P ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC SCI,DEPT CHIM,SYNTHESE ORGAN LAB,SHERBROOKE J1K 2R1,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)94472-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of optically active 14β-hydroxy steroid 9 is reported. This steroid is obtained in only two steps from chiral precursors 6 and 7 via anionic cycloaddition followed by base-catalyzed aldol reaction of triketone 8. © 1990.

引用

页码：3961 / 3964

页数：4

共 9 条

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