DOUBLE-HELICAL DINUCLEAR COPPER(I) COMPLEXES OF MACROCYCLIC BIS(DITHIADIIMINE) LIGANDS

被引：34
|
作者：
COMBA, P
FATH, A
HAMBLEY, TW
RICHENS, DT
机构：
[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA
[2] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 17期
关键词：
COMPLEXES WITH MACROCYCLIC LIGANDS; COPPER COMPOUNDS; HELICAL STRUCTURES; MOLECULAR MODELING; SUPRAMOLECULAR CHEMISTRY;
D O I：
10.1002/anie.199518831
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
32‐ and 34‐membered macrocyclic Schiff base type ligands with (N2S2)2 donor units are synthesized in a high‐yielding [2 + 2] condensation reaction. Coordination of these ligands to copper(I) results in double helical dicopper(I) complexes with a new figure‐of‐eight loop structure (see diagram on the right). (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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收藏
页码：1883 / 1885
页数：3
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