CRYSTAL-STRUCTURE OF THE ORTHOPHOSPHATE RBBAPO4

被引：11

作者：

ELAMMARI, L ^{[1
]}

ELOUADI, B ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST KRISTALLOG,W-7500 KARLSRUHE,GERMANY

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 188卷 / 1-2期

关键词：

D O I：

10.1016/0925-8388(92)90651-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

RbBaPO4 single-crystals were prepared by the flux method. The X-ray diffraction patterns show that this compound crystallizes in the orthorhombic system with Pnma space group and the following unit cell parameters: a = 7.812(2) angstrom, b = 5.740(1) angstrom, c = 10.056(2) angstrom, Z = 4. RbBaPO4 is isostructural with KBaPO4 which derives from the glaserite, where potassium and sodium are substituted by rubidium and barium respectively. The structure is formed by regular PO43- tetrahedra surrounding the Rb+ and Ba2+ cations in ten-fold and nine-fold coordinations respectively.

引用

页码：99 / 101

页数：3

共 7 条

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