ON THE INFLUENCE OF HETEROATOMS IN ALPHA-FUNCTIONALIZED AND BETA-FUNCTIONALIZED ALKYL TRANSITION-METAL COMPOUNDS

被引：43
作者：
STEINBORN, D
机构：
[1] Institut für Anorganische Chemie, Technischen Hochschule Merseburg, Merseburg, D-O-4200, Geusaer Strasse
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期
关键词：
D O I：
10.1002/anie.199204011
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure, stability, and reactivity of alkyl–metal complexes can be critically influenced by the introduction of a hetero atom in the alkyl ligand. Compounds of the type [LxM‐(CH2)m‐YRn] (m ≥ 1; x,n ≥ 0) provide a series for the investigation of the influence of both the heteroatom and the metal in relation to the length of the alkylene bridge. This interest is not purely academic. Functionalized ethene and ethyl palladium complexes play an important role in the synthesis of acetaldehyde by the Wacker process.
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页码：401 / 421
页数：21
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