ON THE INFLUENCE OF HETEROATOMS IN ALPHA-FUNCTIONALIZED AND BETA-FUNCTIONALIZED ALKYL TRANSITION-METAL COMPOUNDS

被引：43
作者：
STEINBORN, D
机构：
[1] Institut für Anorganische Chemie, Technischen Hochschule Merseburg, Merseburg, D-O-4200, Geusaer Strasse
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期
关键词：
D O I：
10.1002/anie.199204011
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure, stability, and reactivity of alkyl–metal complexes can be critically influenced by the introduction of a hetero atom in the alkyl ligand. Compounds of the type [LxM‐(CH2)m‐YRn] (m ≥ 1; x,n ≥ 0) provide a series for the investigation of the influence of both the heteroatom and the metal in relation to the length of the alkylene bridge. This interest is not purely academic. Functionalized ethene and ethyl palladium complexes play an important role in the synthesis of acetaldehyde by the Wacker process.
引用
收藏
页码：401 / 421
页数：21
相关论文
共 317 条
[1]  
ABBENHUIS HCL, 1990, RECL TRAV CHIM PAY B, V109, P361
[2]   SYNTHESES AND PROPERTIES OF AMINOMETHYL COMPLEXES OF MANGANESE AND RHENIUM [J].
ABEL, EW ;
ROWLEY, RJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (11) :1096-1099
[3]   SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O [J].
ADAMS, H ;
BAILEY, NA ;
OSBORN, VA ;
WINTER, MJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10) :2127-2135
[4]   REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH [J].
ADAMS, H ;
BAILEY, NA ;
CAHILL, P ;
ROGERS, D ;
WINTER, MJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10) :2119-2126
[5]  
ADERSEN R, 1975, J ORGANOMET CHEM, V99, pC19
[6]  
AKERMARK B, 1984, J AM CHEM SOC, V106, P5560
[7]   THE MECHANISM OF THE WACKER PROCESS - CORROBORATIVE EVIDENCE FOR DISTAL ADDITION OF WATER AND PALLADIUM [J].
AKERMARK, B ;
SODERBERG, BC ;
HALL, SS .
ORGANOMETALLICS, 1987, 6 (12) :2608-2610
[8]   NUCLEOPHILIC-ADDITION TO PI-OLEFIN-PALLADIUM, PI-ALLYL-PALLADIUM AND SIGMA-ALKYL-PALLADIUM COMPLEXES - EXAMPLES OF UMPOLUNG BY THE USE OF ORGANO-METALLIC REAGENTS [J].
AKERMARK, B ;
BACKVALL, JE ;
ZETTERBERG, K .
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1982, 36 (09) :577-585
[9]   REACTIVITY OF [PT(CH2CL)2(PH2PCH2PPH2-PP')],[PT(CH2BR)2(PH2PCH2PPH2-PP')],[PT(CH2I)2(PH2PCH2PPH2-PP')] - 4-MEMBERED TO 5-MEMBERED RING EXPANSIONS - CRYSTAL-STRUCTURE OF [BIS(DIPHENYLPHOSPHINO)-METHANE-PP']BIS(CHLOROMETHYL)PLATINUM(II) [J].
ALCOCK, NW ;
PRINGLE, PG ;
BERGAMINI, P ;
SOSTERO, S ;
TRAVERSO, O .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05) :1553-1556
[10]   REACTIVITY AND MECHANISM IN THE REACTIONS OF PLATINACYCLOBUTANES TO GIVE ALKENE OR YLIDE COMPLEXES - EVIDENCE FOR ALPHA-ELIMINATION [J].
ALESSA, RJ ;
LING, SSM ;
PUDDEPHATT, RJ .
ORGANOMETALLICS, 1987, 6 (05) :951-959
12345678910