SILACYCLOPROPENE - GENERATION BY HIGH-VACUUM FLASH PYROLYSIS AND MATRIX-SPECTROSCOPIC IDENTIFICATION

被引：18
|
作者：
MAIER, G
PACL, H
REISENAUER, HP
机构：
[1] Institut für Organische Chemie, Universität Giessen, D-35392
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期
关键词：
FLASH PYROLYSIS; PHOTOCHEMISTRY; SILICON COMPOUNDS; STRAINED RINGS;
D O I：
10.1002/anie.199514391
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Since the first synthesis of a silacyclopropene, efforts have been made to prepare the unsubstituted parent compound 3. This goal has finally been achieved: Pyrolytic elimination of trimethylsilane from 1 initially leads to the silanediyl 2, which cyclizes to 3. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
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页码：1439 / 1441
页数：3
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