SYNTHESIS OF ATROPISOMERIC BIPHENYLBISPHOSPHINE, 6,2'-BIS(DIPHENYLPHOSPHINO)-3-METHOXY-2,4-DIMETHYL-4',6'-BIS(TRIFLUOROMETHYL)-1,1'-BIPHENYL (FUPMOP) AND ITS USE IN RUTHENIUM(II)-CATALYZED ASYMMETRIC HYDROGENATION OF A 3-OXO ESTER

被引：0

作者：

MURATA, M ^{[1
]}

MORIMOTO, T ^{[1
]}

ACHIWA, K ^{[1
]}

机构：

[1] UNIV SHIZUOKA,SCH PHARMACEUT SCI,395 YADA,SHIZUOKA 422,JAPAN

来源：

SYNLETT | 1991年 / 11期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New atropisomeric biphenylbisphosphines, 6,2'-bis(diphenylphosphino)-3-methoxy-2,4-dimethyl-4',6'-bis(tri-fluoromethyl)-1,1'-biphenyl (FUPMOP) and 2,2'-bis(diphenylphoshino)-4,6,4',6'-tetrakis(trifluoromethyl)-1,1'-biphenyl (BIFUP), have been prepared from 2-bromo-3,5-bis-(trifluoromethyl)nitrobenzene. The FUPMOP-ruthenium(II) complex proved to be an excellent catalyst for the asymmetric hydrogenation of methyl 3-oxobutanoate.

引用

页码：827 / 829

页数：3

共 5 条

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[4]

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