LASER-INDUCED FLUORESCENCE SPECTROSCOPY AND STRUCTURE OF MICROSOLVATED MOLECULAR CLUSTERS .2. LASER-INDUCED FLUORESCENCE SPECTROSCOPY OF JET-COOLED ETHYL 4-AMINOBENZOATE, METHYL 4-AMINOBENZOATE, 4-AMINOBENZONITRILE AND THEIR DIMETHYLAMINO AND PYRROLIDINO DERIVATIVES

被引：37

作者：

HOWELLS, BD ^{[1
]}

MCCOMBIE, J ^{[1
]}

PALMER, TF ^{[1
]}

SIMONS, JP ^{[1
]}

WALTERS, A ^{[1
]}

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1992年 / 88卷 / 18期

关键词：

D O I：

10.1039/ft9928802595

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An iterative band contour simulation strategy has been applied to the analysis of partially resolved rovibronic bands in the laser-induced fluorescence (LIF) spectra of a range of jet-cooled, substituted aromatic amines (4-dimethylaminobenzonitrile, ethyl 4-dimethylaminobenzoate, methyl 4-dimethylaminobenzoate, 4-aminobenzonitrile, ethyl 4-aminobenzoate, methyl 4-aminobenzoate, 4-pyrrolidinobenzonitrile, ethyl 4-pyrrolidinobenzoate and methyl 4-pyrrolidinobenzoate). A internally consistent set of structural parameters has been obtained which, by appeal to the predictions of molecular orbital and/or molecular mechanics calculations, provides an experimentally based set of molecular structures as well as the resolution and identification of alternative molecular conformers.

引用

页码：2595 / 2601

页数：7

共 34 条

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