DETERMINATION OF NONIONIC SURFACTANTS OF THE ALKYLPHENOL POYLETHOXYLATE TYPE BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

被引：164

作者：

AHEL, M ^{[1
]}

GIGER, W ^{[1
]}

机构：

[1] SWISS FED INST WATER RESOURCES & WATER POLLUT CONTROL,CH-8600 DUBENDORF,SWITZERLAND

来源：

ANALYTICAL CHEMISTRY | 1985年 / 57卷 / 13期

关键词：

CHROMATOGRAPHIC ANALYSIS - Liquid - SURFACE ACTIVE AGENTS;

D O I：

10.1021/ac00290a035

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method is described for the quantitative determination of alkylphenol polyethoxylates (APEO) in synthetic surfactants and in wastewaters. Gaseous stripping into ethyl acetate is employed to extract the analytes from wastewater samples. Normal-phase high-performance liquid chromatography (HP-LC) using bonded-phase aminosilica columns allows the separation and quantitative determination of oligomeric APEO. For the major oligomers relative deviations range from 2 to 10%. Estimated limits of detection for individual oligomers are 1 mu g/L, and recovery of total APEO is 87%.

引用

页码：2584 / 2590

页数：7