ISOMERIZATION OF ALLYL ALCOHOLS WITH RHODIUM(I) COMPLEXES

被引：0
|
作者：
TRZECIAK, AM [1 ]
ZIOLKOWSKI, JJ [1 ]
机构：
[1] UNIWERSYTETU WROCLAWSKIEGO,INST CHEM,UL F JOLIOT CURIE 14,PL-50383 WROCLAW,POLAND
来源：
GAZZETTA CHIMICA ITALIANA | 1994年 / 124卷 / 10期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The results of the isomerization reaction of some allyl alcohols (2-propen-l-ol, 3-buten-2-ol and 1-octen-3-ol) with the Rh(I) complexes HRh(CO)(PPh3)3, HRh{P(OPh)3}4, Rh{P(OPh)3}4ClO4 are presented. The mechanism of the Rh{P(OPh)3}3{P(OPh)2(OC6H4)}-catalyzed isomerization is discussed.
引用
收藏
页码：403 / 409
页数：7
相关论文
共 50 条
  • [1] ASYMMETRIC ISOMERIZATION OF ALLYL ALCOHOLS WITH RHODIUM(I)-CHIRAL PHOSPHINE COMPLEXES
    BOTTEGHI, C
    GIACOMELLI, G
    GAZZETTA CHIMICA ITALIANA, 1976, 106 (11-1): : 1131 - 1134
  • [2] RAPID ISOMERIZATION OF ALLYLIC ALCOHOLS WITH IRIDIUM(I) AND RHODIUM(I) COMPLEXES AT AMBIENT TEMPERATURE
    Chin, Chong Shik
    Park, Jeonghan
    Kim, Choongil
    Lee, Sun Yeoul
    Shin, Jun Ho
    Kim, Joong Bae
    CATALYSIS LETTERS, 1988, 1 (6-7) : 203 - 205
  • [3] RHODIUM(I)-CATALYZED BIPHASIC ISOMERIZATION OF ALLYLIC ALCOHOLS
    ALPER, H
    HACHEM, K
    JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (11): : 2269 - 2270
  • [4] A VERSATILE ROUTE TO SILYLSUBSTITUTED KETONES BY RHODIUM CATALYZED ISOMERIZATION OF SILYLATED ALLYL ALCOHOLS
    SATO, S
    OKADA, H
    MATSUDA, I
    IZUMI, Y
    TETRAHEDRON LETTERS, 1984, 25 (07) : 769 - 770
  • [5] Single Site Supported Cationic Rhodium(I) Complexes for the Selective Redox Isomerization of Allylic Alcohols
    Sahoo, Suman
    Lundberg, Helena
    Eden, Mattias
    Ahlsten, Nanna
    Wan, Wei
    Zou, Xiaodong
    Martin-Matute, Belen
    CHEMCATCHEM, 2012, 4 (02) : 243 - 250
  • [6] Isomerization of di- and multifunctional allyl compounds catalyzed by ruthenium and rhodium complexes
    Krompiec, S
    Suwinski, J
    Grobelny, J
    Wagner, P
    POLISH JOURNAL OF CHEMISTRY, 1997, 71 (06) : 747 - 753
  • [7] Isomerization of aldehydes catalyzed by rhodium(I) olefin complexes
    Lenges, CP
    Brookhart, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1999, 38 (23) : 3533 - 3537
  • [8] DECARBONYLATION OF ALLYLIC ALCOHOLS USING RHODIUM(I) COMPLEXES
    EMERY, A
    OEHLSCHL.AC
    UNRAU, AM
    TETRAHEDRON LETTERS, 1970, (50) : 4401 - &
  • [9] REACTIONS OF ALCOHOLS WITH DIOLEFINS CATALYZED BY COPPER(I) AND RHODIUM(I) COMPLEXES
    TAYLOR, BW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, : 53 - &
  • [10] Efficient isomerization of allylic alcohols to saturated carbonyl compounds by activated rhodium and ruthenium complexes
    Uma, R
    Davies, MK
    Crévisy, C
    Grée, R
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 2001 (16) : 3141 - 3146
12345