7,10-DIHYDROXY-8(E)-OCTADECANOIC ACID - STEREOCHEMISTRY AND A NOVEL DERIVATIVE, 7,10-DIHYDROXYOCTADECANOIC ACID

被引：16

作者：

KNOTHE, G

BAGBY, MO

PETERSON, RE

HOU, CT

机构：

[1] Oil Chemical Research, National Center for Agricultural Utilization Research, Agricultural Research Service, U.S. Department of Agriculture, Peoria, 61604, IL

[2] Bioactive Constituents Research, National Center for Agricultural Utilization Research, Agricultural Research Service, U.S. Department of Agriculture, Peoria, 61604, IL

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1992年 / 69卷 / 04期

关键词：

ABSOLUTE CONFIGURATION; CIRCULAR DICHROISM; 7,10-DIHYDROXY-8(E)-OCTADECENOIC ACID; 7,10-DIHYDROXYOCTADECANOIC ACID; DIIMIDE; HYDRAZINE; HYDROGENATION; SPECIFIC OPTICAL ROTATION;

D O I：

10.1007/BF02636070

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

7,10-Dihydroxy-8(E)-octadecenoic acid (obtained by bioconversion of oleic acid with the bacterial strain PR3) was hydrogenated with hydrazine hydrate under air in ethanolic solution to give a novel compound, 7,10-dihydroxyoctadecanoic acid. The absolute configuration of both compounds was determined with the aid of circular dichroism to be R,R. A different purification method for 7,10-dihydroxy-8(E)-octadecenoic acid is described.

引用

页码：367 / 371

页数：5

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