ONE-STEP SYNTHESIS OF POLY(METHACRYLIC ACID) MACROMONOMERS AND APPLICATION TO SOAP-FREE EMULSION COPOLYMERIZATION WITH STYRENE

被引：9

作者：

ITO, K

SABAO, K

KAWAGUCHI, S

机构：

[1] Department of Materials Science, Toyohashi University of Technology, Toyohashi, 441, Tempaku-cho

来源：

MACROMOLECULAR SYMPOSIA | 1995年 / 91卷

关键词：

D O I：

10.1002/masy.19950910107

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Allylic sulfides such as alpha-(tert-butylthiomethyl)styrene and alpha-(2-hydroxyethylthiomethyl)styrene worked as effective chain transfer agents in the radical polymerization of methacrylic acid, to afford a one-step synthesis of water-soluble macromonomers with the 2-phenylallyl end groups. The macromonomers were found to be effective, particularly in the partially neutralized form, in emulsion copolymerization with styrene in water, to give stable emulsions with nearly monodisperse, submicron-sized particles. The microspheres thus obtained are considered to have carboxyl groups densely bound on the surface as a result of an organized copolymerization.

引用

页码：65 / 72

页数：8

共 50 条

[41] Facile one-pot/one-step synthesis of heterotelechelic N-acylated poly(aminoester) macromonomers for carboxylic acid decorated comb polymers
de Jongh, Patrick A. J. M.
Bennett, Mechelle R.
Sulley, Greg S.
Wilson, Paul
Davis, Thomas P.
Haddleton, David M.
Kempe, Kristian
POLYMER CHEMISTRY, 2016, 7 (44) : 6703 - 6707
[42] Mechanism of polymer particles formation during the soap-free emulsion terpolymerization of styrene - acrylic acid - N -(isopropyl acrylamide) for photonic crystals fabrication
Rusen, Edina
Mocanu, Alexandra
Somoghi, Raluca
Culita, Daniela C.
Mitran, Raul Augustin
Dinescu, Adrian
Matei, Andreea
Diacon, Aurel
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2021, 614
[43] Modification of Halloysite Nanotubes with Poly(styrene-butyl acrylate-acrylic acid) via In Situ Soap-Free Graft Polymerization
Zhang, Yanwu
Jiang, Junqing
Liang, Qihui
Zhang, Bing
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 117 (05) : 3054 - 3059
[44] RETRACTED: Size-controlled spherical polymer nanoparticles: Synthesis with tandem acoustic emulsification followed by soap-free emulsion polymerization and one-step fabrication of colloidal crystal films of various colors (Retracted Article)
Hirai, Yuki
Nakabayashi, Koji
Kojima, Maya
Atobe, Mahito
ULTRASONICS SONOCHEMISTRY, 2014, 21 (06) : 1921 - 1927
[45] One-Step Synthesis of MnO2 Particles Distributed Polyaniline-Poly(styrene-sulfonic acid)
Liu, Feng-Jiin
SYNTHETIC METALS, 2009, 159 (17-18) : 1896 - 1899
[46] Controlled Synthesis of Nano-Sized Cationic Soap-Free Polystyrene/Poly(methyl methacrylate) Latexes via Reversible Addition-Fragmentation Chain Transfer Mediated Emulsion Copolymerization
Xu, Jianxiong
Tong, Chao
Du, Guo
Liu, Weiwei
Li, Na
NANOSCIENCE AND NANOTECHNOLOGY LETTERS, 2016, 8 (06) : 514 - 520
[47] Synthesis of submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene particles by seeded soap-free emulsion polymerization
Shin Ichi Kuroda
ChineseChemicalLetters, 2011, 22 (09) : 1127 - 1129
[48] Synthesis of submicron-sized peanut-shaped poly(methyl methacrylate)/polystyrene particles by seeded soap-free emulsion polymerization
Shi, Shan
Wang, Tao
Tang, Yan Tao
Zhou, Li Min
Kuroda, Shin Ichi
CHINESE CHEMICAL LETTERS, 2011, 22 (09) : 1127 - 1129
[49] PREPARATION OF MICRON-SIZED NONSPHERICAL POLYSTYRENE/POLY(STYRENE-co-ETHYLENEGLYCOL DIMETHACRYLATE) PARTICLES BY SEEDED SOAP-FREE EMULSION POLYMERIZATION附视频
石山
Shinichi Kuroda
Chinese Journal of Polymer Science, 2011, (05) : 634 - 638
[50] Synthesis of hemispherical poly(2-hydroxylethyl methacrylate-co-methyl methacrylate)/poly(styrene-co-glycidyl methacrylate) composite particles with heterobifunctional groups by soap-free seeded emulsion polymerization
Du, YZ
Tomohiro, T
Kodaka, M
MACROMOLECULES, 2004, 37 (03) : 803 - 812

← 1 2 3 4 5 →