KINETICS AND MECHANISM OF THE DEHYDRATION OF AMMONIUM OXALATE MONOHYDRATE

被引：6

作者：

HOUSE, JE

RALSTON, RP

机构：

[1] Department of Chemistry, Illinois State University, Normal

来源：

THERMOCHIMICA ACTA | 1993年 / 214卷 / 02期

关键词：

D O I：

10.1016/0040-6031(93)80063-G

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The dehydration of (NH4)2C2O4 . H2O has been studied by isothermal and non-isothermal TG. From the non-isothermal experiments, the best-fitting rate law appears to be Al.5, A3, or D3. Data from isothermal experiments gave the best fit with an R2 rate law. A value of 73 kJ mol-1 was found for the activation energy, and the nature of the variation between runs was explored.

引用

页码：255 / 260

页数：6

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