OXYGEN-TRANSFER FROM AMIDOXIMES TO MO(II) CENTERS - SYNTHESIS AND X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF [CH3C(NH2)2]2[MO4O12(CH3C(NH2)NO)2].2C2H5OH

被引：10
|
作者：
CHILOU, V [1 ]
GOUZERH, P [1 ]
JEANNIN, Y [1 ]
KNOBLER, CB [1 ]
机构：
[1] UNIV PARIS 06,CHIM MET TRANSIT LAB,CNRS,URA 419,4 PL JUSSIEU,F-75252 PARIS 05,FRANCE
来源：
INORGANICA CHIMICA ACTA | 1990年 / 178卷 / 01期
关键词：
D O I：
10.1016/S0020-1693(00)88128-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The deoxygenation of amidoximes has been observed with two molybdenum(II) complexes. [CH3C(NH2)2]2[Mo4O12{CH3C(NH2)NO}2].2C2H5OH was obtained from [Mo(NO)(acac)2-{CH3C(NH2)NO}] and C6H5CONHNH2, and characterized by X-ray crystallography. It crystallizes in the orthorhombic space group Pcab, with a = 13.385(5), b = 12.172(3), c = 18.358(5) angstrom. The structure was refined to R = 0.031 (R(w) = 0.039) for 2140 reflections with I > 3.0-sigma(I). The crystals contain centrosymmetrical cyclic organotetramolybdates which are connected to acetaminidium cations and solvent molecules through N-H...O and O-H...O intermolecular hydrogen bonds.
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页码：23 / 25
页数：3
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