A GUIDANCE FOR STABLE METALLIC CONDUCTIVITY IN COPPER-SALTS OF N,N'-DICYANOBENZOQUINONEDIIMINES (DCNQIS)

被引：35

作者：

ERK, P

MEIXNER, H

METZENTHIN, T

HUNIG, S

LANGOHR, U

VONSCHUTZ, JU

WERNER, HP

WOLF, HC

BURKERT, R

HELBERG, HW

SCHAUMBURG, G

机构：

[1] UNIV WURZBURG,INST ORGAN CHEM,W-8700 WURZBURG,GERMANY

[2] UNIV STUTTGART,INST PHYS 3,W-7000 STUTTGART 80,GERMANY

[3] UNIV GOTTINGEN,INST PHYS 3,W-3400 GOTTINGEN,GERMANY

来源：

ADVANCED MATERIALS | 1991年 / 3卷 / 06期

关键词：

D O I：

10.1002/adma.19910030610

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical anion salts of 2,5-substituted N,N'-dicyanoquinonediimines (DCNQIs) with various counterions represent a new class of highly conducting organic materials. Among the copper salts of the DCNQIs (see figure) five new radical anion salts with stable metallic behavior are presented. A comparison of structural details with physical properties reveals their stable metallic state to be conserved by tight crystal packing, which is dependent on the size of the substituents on the DCNQIs.

引用

页码：311 / 315

页数：5

共 33 条

[1]

Aum?ller A., 1986, ANGEW CHEM, V98, P759

[2] A RADICAL-ANION SALT OF 2,5-DIMETHYL-N,N'-DICYANOQUINONEDIIMINE WITH EXTREMELY HIGH ELECTRICAL-CONDUCTIVITY [J].

AUMULLER, A ;

ERK, P ;

KLEBE, G ;

HUNIG, S ;

VONSCHUTZ, JU ;

WERNER, HP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (08) :740-741

[3]

BAUER T, 1991, THESIS U WURZBURG

[4] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[5] COMPARISON OF EXPERIMENTAL DETERMINATIONS OF ELECTRON AFFINITIES OF PI CHARGE-TRANSFER COMPLEX ACCEPTORS [J].

CHEN, ECM ;

WENTWORTH, WE .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (08) :3183-3191

[6]

Erk, 1989, ANGEW CHEM, V101, P1297

[7]

ERK P, 1988, LIEBIGS ANN CHEM, P157

[8] THE COPPER SALT OF 2-IODO-5-METHYL-N,N'-DICYANOQUINONEDIIMINE - A RADICAL-ANION SALT EXHIBITING METALLIC CONDUCTIVITY DOWN TO LOW-TEMPERATURES [J].

ERK, P ;

HUNIG, S ;

VONSCHUTZ, JU ;

WERNER, HP ;

WOLF, HC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (02) :267-268

[9] BINARY-ALLOYS OF 2,5-DISUBSTITUTED DCNQI RADICAL-ANION SALTS OF COPPER AND THEIR ELECTRICAL-CONDUCTIVITY [J].

ERK, P ;

GROSS, HJ ;

HUNIG, S ;

LANGOHR, U ;

MEIXNER, H ;

WERNER, HP ;

VONSCHUTZ, JU ;

WOLF, HC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09) :1245-1246

[10]

ERK P, 1991, ADV MATER, V3, P225

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