SILANE CROSS-LINKING OF POLYOLEFINS - OBSERVATIONS ON THE TIN CATALYST EMPLOYED

被引：25
|
作者：
TOYNBEE, J
机构：
[1] BICC Cables Ltd, Wrexham Technology Centre, Wrexham
来源：
POLYMER | 1994年 / 35卷 / 02期
关键词：
CROSS-LINKING; POLY-OLEFINS; CATALYST;
D O I：
10.1016/0032-3861(94)90717-X
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
FTi.r. has shown that the dibutyltin dilaurate catalyst employed in silane crosslinking of polyolefins exists in true equilibrium. The position of this equilibrium is highly dependant upon the polarity of the surrounding medium, which in turn may have a profound effect on the rate of crosslinking in such systems.
引用
收藏
页码：438 / 440
页数：3
相关论文
共 50 条
  • [21] Cross-linking reconsidered: Binding and cross-linking fields and the cellular response
    Sulzer, B
    DeBoer, RJ
    Perelson, AS
    BIOPHYSICAL JOURNAL, 1996, 70 (03) : 1154 - 1168
  • [22] EPR studies of peroxide decomposition, radical formation and reactions relevant to cross-linking and grafting in polyolefins
    Camara, Susana
    Gilbert, Bruce C.
    Meier, Robert J.
    van Duin, Martin
    Whitwood, Adrian C.
    POLYMER, 2006, 47 (13) : 4683 - 4693
  • [23] KINETICS OF FREE-RADICAL MODIFICATION OF POLYOLEFINS IN EXTRUDERS - CHAIN SCISSION, CROSS-LINKING AND GRAFTING
    HAMIELEC, AE
    GLOOR, PE
    ZHU, S
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1991, 69 (03): : 611 - 618
  • [24] Reinforced and superinsulating silica aerogel through in situ cross-linking with silane terminated prepolymers
    Iswar, Subramaniam
    Snellings, Geert M. B. F.
    Zhao, Shanyu
    Erni, Rolf
    Bahk, Yeon Kyoung
    Wang, Jing
    Lattuada, Marco
    Koebel, Matthias M.
    Malfait, Wim J.
    ACTA MATERIALIA, 2018, 147 : 322 - 328
  • [25] Mechanism of a one-step method for preparing silane grafting and cross-linking polyprlopylene
    Yang, Shujing
    Song, Guojun
    Zhao, Yunguo
    Yang, Chao
    She, Xilin
    POLYMER ENGINEERING AND SCIENCE, 2007, 47 (07): : 1004 - 1008
  • [26] Preparation of graphene/Al composites with a lamellar structure by silane cross-linking graphene oxide
    Wang, Bohan
    Liu, Jiaming
    Yue, Shipeng
    Wang, Xianlong
    Zhang, Yubo
    Fu, Ying
    Li, Tingju
    Wang, Tongmin
    JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2021, 13 : 2433 - 2441
  • [27] Cross-linking electrospinning
    Han, Wei-Hua
    Wang, Qing-Yu
    Kang, Yuan-Yi
    Shi, Li-Rui
    Long, Yu
    Zhou, Xin
    Hao, Chun-Cheng
    NANOSCALE, 2023, 15 (38) : 15513 - 15551
  • [28] Collagen Cross-Linking
    Kymionis, George D.
    Portaliou, Dimitra M.
    OPHTHALMOLOGY, 2010, 117 (10) : 2040 - +
  • [29] CHEMICAL CROSS-LINKING
    BLUESTEI.AC
    RUBBER AGE, 1968, 100 (01): : 72 - &
  • [30] COLLAGEN CROSS-LINKING
    RICARDBLUM, S
    VILLE, G
    INTERNATIONAL JOURNAL OF BIOCHEMISTRY, 1989, 21 (11): : 1185 - 1189
12345