THE REACTIONS OF SOME PROTECTED AND UNPROTECTED MONOSACCHARIDES WITH M(NO)(HB(3,5-ME2C3HN2)3)X2 (M=MO, X=CL, BR, I - M=W, X=CL)

被引:5
作者
COE, EM
JONES, CJ
MCCLEVERTY, JA
机构
[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND
[2] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND
关键词
D O I
10.1016/S0277-5387(00)83653-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions between [M(NO){HB(3,5-Me2C3HN2)3}X2] (M = Mo, X = Cl, Br, 1; M = W, X = Cl) and the monosaccharides 2,3:4,5-di-O-iso-propylidene-beta-D-fructopyranose, 2,3: 5,6-di-O-isopropylidene-alpha-D-mannofuranose, methyl-alpha-D-glucopyranoside and D-(+)-mannofuranose have been investigated and the complexes [M(NO){HB(3,5-Me2C3HN2)3}X(OR)] (M = Mo, X = Cl, Br, 1; M = W, X = Cl; ROH = 2,3:4,5-di-O-isopropylidene-beta-D-fructopyranose) have been isolated as mixtures of diastereoisomers.
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页码:3129 / 3134
页数:6
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