INFRARED SPECTROSCOPIC EVIDENCE FOR MONOMERIC HGACL2 IN SOLID ARGON

被引：24

作者：

KOPPE, R ^{[1
]}

TACKE, M ^{[1
]}

SCHNOCKEL, H ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1991年 / 605卷 / 14期

关键词：

GALLIUM HYDROGEN DICHLORIDE; MATRIX ISOLATION; IR SPECTRA; NORMAL COORDINATE ANALYSIS;

D O I：

10.1002/zaac.19916050104

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Molecular HGaCl2 is found in a matrix between the hightemperature molecule GaCl and HCl. A structure analogous to that of phosgene can be derived from the isotopical shifts (H/D, Ga-69/Ga-71 and Cl-35/Cl-37) within the IR spectra. The normal coordinate analysis results for the GaCl force constant a value of 2.52 mdyn/angstrom and for the GaH force constant a value of 2.38 mdyn/angstrom.

引用

页码：35 / 41

页数：7

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