METASTABLE DYNAMICS ABOVE THE GLASS-TRANSITION

The element of metastability is incorporated in the fluctuating nonlinear hydrodynamic description of the mode coupling theory (MCT) of the liquid-glass transition. This is achieved through the introduction of defect density variable n into the set of slow variables with mass density ρ and momentum density g. As a first approximation, we consider the case where motions associated with n are much slower than those associated with ρ. Self-consistently, assuming one is near a critical surface in the MCT sense, we find that the observed slowing down of the dynamics corresponds to a certain limit of a very shallow metastable well and a weak coupling between ρ and n. The metastability parameters, as well as the exponent describing the observed sequence of time relaxations, are given as smooth functions of the temperature without any evidence of a special temperature. We then investigate the case where the defect dynamics is included. We find that the slowing down of the dynamics corresponds to the system arranging itself such that the kinetic coefficient governing the diffusion of the defects approaches from above a small temperature-dependent value. © 1995 The American Physical Society.