PREPARATION OF CHIRAL DIOLS BY THE OSMIUM-CATALYZED, INDIRECT ANODIC-OXIDATION OF OLEFINS

被引：30

作者：

AMUNDSEN, AR

BALKO, EN

机构：

[1] Corporate Research Department, Engelhard Corporation, Iselin, 08830, NJ

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1992年 / 22卷 / 09期

关键词：

D O I：

10.1007/BF01023722

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Chiral diols have been prepared by the osmium-catalysed, indirect anodic oxidation of the corresponding olefin. Diol yields were high in all cases; enantiomeric selectivity was related to the bulk of substituent groups borne by the alkene. Overoxidation of the product diol to the corresponding diketone was the principal contributor to process inefficiency.

引用

页码：810 / 816

页数：7

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