[CP(2)TI(C-CTBU)(2)] AS AN ALKYNYL TRANSFER REAGENT - SYNTHESIS AND CHARACTERIZATION OF THE ASYMMETRICALLY BRIDGED HETERODIMETALLIC COMPLEX [CP(2)TI(C-CTBU)(2)PT(PPH(3))]CENTER-DOT-0.5 THF

被引：29

作者：

BERENGUER, JR

FORNIES, J

LALINDE, E

MARTIN, A

机构：

[1] UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN,E-50009 ZARAGOZA,SPAIN

[2] UNIV LA RIOJA,DEPT QUIM,E-26001 LOGRONO,SPAIN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 20期

关键词：

D O I：

10.1002/anie.199420831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination in A and B are not the only modes possible when dialkynylbis(cyclopentadienyl)titanium complexes coordinate other metal complex fragments. The reaction of [Cp2Ti(CCtBu)2] with [Pt(C2H4)(PPh3)2] affords a dinuclear complex which has structure C in the solid state. Dynamic processes are evident for this complex in solution. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：2083 / 2085

页数：3

相关论文

共 17 条

[1]

BAIRD MC, 1968, PROGR INORG CHEM, V9, P1

[2] UNUSUAL BRIDGING OF THE METAL CENTERS IN A HETEROMETALLIC TITANIUM PLATINUM COMPLEX - X-RAY STRUCTURE OF [CP2TI(MU-2-ETA-1-CC-T-BU)2PT(C6F5)2].CH2CL2 [J].

BERENGUER, JR ;

FALVELLO, LR ;

FORNIES, J ;

LALINDE, E ;

TOMAS, M .

ORGANOMETALLICS, 1993, 12 (01) :6-7

[3] REACTIONS OF BIS-(ETHYLENE)(TERTIARY PHOSPHINE)PLATINUM COMPLEXES WITH PHENYLETHYNYL DERIVATIVES OF TITANIUM AND SILICON - CRYSTAL-STRUCTURE OF (MU-DIMETHYLSILANEDIYL)(SIGMA-PHENYLETHYNYL)[MU-(1-SIGMA-1-2-ETA-PHENYLETHYNYL)]-BIS(TRICYCLOHEXYLPHOSPHINE)DIPLATINUM (PT-PT) [J].

CIRIANO, M ;

HOWARD, JAK ;

SPENCER, JL ;

STONE, FGA ;

WADEPOHL, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (11) :1749-1756

[4] PI-CONJUGATION AND DYNAMIC BEHAVIOR IN DOUBLY ACETYLIDE-BRIDGED BINUCLEAR GROUP-4 BENT METALLOCENE COMPLEXES [J].

ERKER, G ;

FROMBERG, W ;

BENN, R ;

MYNOTT, R ;

ANGERMUND, K ;

KRUGER, C .

ORGANOMETALLICS, 1989, 8 (04) :911-920

[5] UNUSUAL BRIDGING OF THE METAL CENTERS IN DIMERIC BIS(ETA-METHYLCYCLOPENTADIENYL)PHENYLETHYNYLZIRCONIUM [J].

ERKER, G ;

FROMBERG, W ;

MYNOTT, R ;

GABOR, B ;

KRUGER, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (05) :463-465

[6]

ERKER G, 1986, ANGEW CHEM, V98, P458

[7] PREPARATION OF DOUBLY ACETYLIDE-BRIDGED BINUCLEAR PLATINUM PLATINUM AND PLATINUM PALLADIUM COMPLEXES - STRUCTURES OF [((DPPE)PT(CCPH)2)PT(C6F5)2] AND (PMEPH3)2[(C6F5)2PT(MU-CCPH)2PT(C6F5)2] [J].

FORNIES, J ;

GOMEZSASO, MA ;

LALINDE, E ;

MARTINEZ, F ;

MORENO, MT .

ORGANOMETALLICS, 1992, 11 (08) :2873-2883

[8]

HEAD RA, 1990, INORG SYNTH, V28, P134

[9] BIS(ALKYNYL)TITANOCENE COMPLEXES - ORGANOMETALLIC BIDENTATE CHELATE LIGANDS [J].

LANG, H ;

ZSOLNAI, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 406 (1-2) :C5-C8

[10] STABLE BIS(ALKYNYL)TITANOCENE COMPLEXES OF FECL2 AND CUCL [J].

LANG, H ;

HERRES, M ;

ZSOLNAI, L ;

IMHOF, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 409 (03) :C7-C11