ALTERNATING-CURRENT VOLTAMMETRY WITH CARBON-FIBER MICROELECTRODES

被引：36

作者：

BARANSKI, AS

机构：

[1] Univ of Saskatchewan, Dep of, Chemistry, Saskatoon, Sask, Can, Univ of Saskatchewan, Dep of Chemistry, Saskatoon, Sask, Can

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1986年 / 133卷 / 01期

关键词：

ELECTROCHEMISTRY - ELECTRODES - ORGANIC COMPOUNDS;

D O I：

10.1149/1.2108552

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A simple system comprising a lock-in amplifier and a current preamplifier has been used to study the ac voltammetry of ferrocene in acetonitrile with carbon fiber microelectrodes. The measurements have been carried out in the frequency range 1 Hz-100 kHz and for depolarizer concentrations 2 multiplied by 10** minus **7-10** minus **2 M. Experimental data are compared with results of theoretical calculations. Nonfaradaic processes occurring at carbon fiber microelectrodes in acetonitrile solutions are also discussed.

引用

页码：93 / 97

页数：5

共 12 条

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