CATIONIC INTERMEDIATES IN OXIDATIVE ADDITION-REACTIONS OF ALKYL-HALIDES TO D8 COMPLEXES - EVIDENCE FOR THE SN2 MECHANISM

被引：131

作者：

CRESPO, M ^{[1
]}

PUDDEPHATT, RJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO, DEPT CHEM, LONDON N6A 5B7, ONTARIO, CANADA

来源：

ORGANOMETALLICS | 1987年 / 6卷 / 12期

关键词：

D O I：

10.1021/om00155a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2548 / 2550

页数：3

共 39 条

[31] A theoretical study of [M(PH3)4] (M = Ru or Fe), models for the highly reactive d8 intermediates [M(dmpe)2] (dmpe = Me2PCH2-CH2PMe2).: Zero activation energies for addition of CO and oxidative addition of H2
Macgregor, SA
Eisenstein, O
Whittlesey, MK
Perutz, RN
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (02): : 291 - 300
[32] REACTIONS OF [ET4N]3[BI(FE(CO)4)4] WITH ALKYL-HALIDES OR DIHALIDES - A GENERAL-METHOD FOR THE SYNTHESIS OF ANIONIC COMPLEXES OF THE TYPE [ET4N]2[RBI(FE(CO)4)3] AND THE CYCLIC COMPLEXES R2BI2FE2(CO)8
SHIEH, MH
LIOU, YT
JENG, BW
ORGANOMETALLICS, 1993, 12 (12) : 4926 - 4929
[33] DINUCLEAR-BRIDGED D8 METAL-COMPLEXES .8. STUDY OF THE OXIDATIVE ADDITION-REACTION AT A SINGLE METAL CENTER - CRYSTAL-STRUCTURE OF [RH2(MU-SBUT)2(CO)(PME2PH)2(COCH3.)I]
MAYANZA, A
BONNET, JJ
GALY, J
KALCK, P
POILBLANC, R
JOURNAL OF CHEMICAL RESEARCH-S, 1980, (04): : 146 - 146
[34] ORGANOLANTHANIDE AND ORGANOACTINIDE OXIDATIVE ADDITIONS EXHIBITING ENHANCED REACTIVITY .5. STOICHIOMETRY, KINETIC, AND MECHANISTIC STUDIES OF (C5ME5)2YBII.OET2 OXIDATIVE-ADDITION REACTIONS AND OF (C5ME5)2YBIIIR (R = R, X) YBIII-GRIGNARD REACTIONS WITH ALKYL AND ARYL HALIDES - EVIDENCE FOR THE DOMINANCE OF INNER-SPHERE MECHANISMS
FINKE, RG
KEENAN, SR
WATSON, PL
ORGANOMETALLICS, 1989, 8 (02) : 263 - 277
[35] THE 1ST MONOMERIC PROCHIRAL TIN(II) COMPLEXES SN[N(SIME3)2]X [X = OC6H2BU(T)2-2,6-ME-4, 1 OR NCME2(CH2)3CME2, 2] - THE X-RAY STRUCTURE OF 1 AND OXIDATIVE ADDITION-REACTIONS OF 2
BRAUNSCHWEIG, H
CHORLEY, RW
HITCHCOCK, PB
LAPPERT, MF
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (18) : 1311 - 1313
[36] PREPARATION AND REACTIVITY OF DINUCLEAR RUII COMPLEXES WITH BRIDGING THIOLATE LIGANDS [CP-ASTERISK-RU(MU-SR)2RUCP-ASTERISK] (CP-ASTERISK = ETA-5-C5ME5 - R=(I)PR, (T)BU, 2,6-ME2C6H3) - OXIDATIVE ADDITION OF ALKYL-HALIDES AT THE DIRUTHENIUM CENTER
TAKAHASHI, A
MIZOBE, Y
MATSUZAKA, H
DEV, S
HIDAI, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 456 (02) : 243 - 253
[37] ORGANOLANTHANIDE AND ORGANOACTINIDE OXIDATIVE ADDITIONS EXHIBITING ENHANCED REACTIVITY .3. PRODUCTS AND STOICHIOMETRIES FOR THE ADDITION OF ALKYL AND ARYL HALIDES TO (C5ME5)2YBII.OET2 AND EVIDENCE FOR FACILE, INNER-SPHERE (C5ME5)2YBIIIR AND (C5ME5)2YBIIIX + RX YBIII GRIGNARD REACTIONS
FINKE, RG
KEENAN, SR
SCHIRALDI, DA
WATSON, PL
ORGANOMETALLICS, 1986, 5 (03) : 598 - 601
[38] ELECTROPHILIC CLEAVAGE OF THE ALKYL-METAL BOND IN THE COMPLEXES, CP-STAR-OS(CO)LR(CP-STAR=ETA-5-C5ME5, L= CO, PME2PH, R= ME, ET, I-PR, CH2PH) - EVIDENCE FOR THE FORMATION OF INTERMEDIATES VIA OXIDATIVE ADDITION OF THE ELECTROPHILE TO THE OSMIUM
JOHNSTON, LJ
BAIRD, MC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 444 - INOR
[39] CHEMISTRY OF LOW-VALENT METAL ISOCYANIDE COMPLEXES .2. OXIDATIVE REACTIONS OF PENTAKIS(TERT-BUTYL ISOCYANIDE)IRON WITH ALKYL, ALLYL, BENZYL, FLUOROALKYL, AND PENTAFLUOROPHENYL HALIDES, AND WITH TRIMETHYLOXONIUM TETRAFLUOROBORATE AND DIPHENYLACETYLENE - EVIDENCE FOR ISOCYANIDE INSERTION REACTIONS, AND THE MOLECULAR-STRUCTURE OF [FE(CNBUT)3-[1-4-ETA-C(=NBUT)=C(PH)C(PH)=C(=NBUT)]]M
BASSETT, JM
GREEN, M
HOWARD, JAK
STONE, FGA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (09): : 1779 - 1788

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