CATIONIC INTERMEDIATES IN OXIDATIVE ADDITION-REACTIONS OF ALKYL-HALIDES TO D8 COMPLEXES - EVIDENCE FOR THE SN2 MECHANISM

被引：131

作者：

CRESPO, M ^{[1
]}

PUDDEPHATT, RJ ^{[1
]}

机构：

[1] UNIV WESTERN ONTARIO, DEPT CHEM, LONDON N6A 5B7, ONTARIO, CANADA

来源：

ORGANOMETALLICS | 1987年 / 6卷 / 12期

关键词：

D O I：

10.1021/om00155a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2548 / 2550

页数：3

共 39 条

[21] MECHANISM OF BIMOLECULAR NUCLEOPHILIC-SUBSTITUTION .9. STEREOCHEMICAL COURSE OF ORTHO-ALKYLATION OF PHENOXIDE ION WITH OPTICALLY-ACTIVE ALKYL-HALIDES UNDER SN2 REACTION CONDITIONS
OKAMOTO, K
KINOSHITA, T
OISHI, T
MORIYAMA, T
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (05): : 453 - 459
[22] DICARBONYLRHODIUM(I) COMPLEXES OF POLYPYRROLE MACROCYCLES .2. OXIDATIVE ADDITION-REACTIONS WITH ALDEHYDES, FORMATES, BETA-OXO-ESTERS, METHYL KETONES, AND ARYL HALIDES
ABEYSEKERA, AM
GRIGG, R
TROCHAGRIMSHAW, J
VISWANATHA, V
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (12): : 1395 - 1403
[23] OXIDATIVE ADDITION-REACTIONS OF ETA-5-C5ME5OS(CO)(PME2PH)ME - ISOLATION OF INTERMEDIATES DURING ALKYL METAL ELECTROPHILIC CLEAVAGE REACTIONS
SANDERSON, LJ
BAIRD, MC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 307 (01) : C1 - C4
[24] Theoretical investigation of ion pair SN2 reactions of alkali isothiocyanates with alkyl halides.: Part 1.: Reaction of lithium isothiocyanate and methyl fluoride with inversion mechanism
Zhu, HJ
Ren, Y
Ren, J
Chu, SY
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2005, 101 (01) : 104 - 112
[25] (ALKYLPEROXO)PLATINUM(IV) COMPLEXES FORMED BY OXIDATIVE ADDITION OF ALKYL-HALIDES IN THE PRESENCE OF OXYGEN - THE MECHANISM OF REACTION AND THE STRUCTURE OF TRANS-IODO(ISOPROPYLPEROXO)DIMETHYL(1,10-PHENANTHROLINE)-PLATINUM(IV)
FERGUSON, G
MONAGHAN, PK
PARVEZ, M
PUDDEPHATT, RJ
ORGANOMETALLICS, 1985, 4 (09) : 1669 - 1674
[26] OXIDATIVE ADDITION OF FUNCTIONALIZED ALKYL-HALIDES TO IRIDIUM(I) COMPLEXES IRCL(CO)PMEPH2(2), IRCL(CO)PME2PH2, IRCL(CO)PME3(2)
BENNETT, MA
CRISP, GT
AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (09) : 1363 - 1375
[27] THERMAL-REACTIONS BETWEEN [MN2(CO)8(PBU3)2] AND ALKYL-HALIDES - EVIDENCE FOR AN OUTER-SPHERE ELECTRON-TRANSFER PROCESS
DAVIS, R
WILSON, FIC
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (01) : 55 - 63
[28] LOW-VALENT RHENIUM-OXO COMPLEXES .11. REACTIONS OF THE LOW-VALENT RHENIUM OXO ANIONS NARE(O)(RCCR)2 WITH ALKYL AND ARYL HALIDES - EVIDENCE FOR BOTH SN2 AND RADICAL MECHANISMS
CONRY, RR
MAYER, JM
ORGANOMETALLICS, 1991, 10 (09) : 3160 - 3166
[29] Mechanism of SN2 alkylation reactions of lithium organocuprate clusters with alkyl halides and epoxides.: Solvent effects, BF3 effects, and trans-diaxial epoxide opening
Mori, S
Nakamura, E
Morokuma, K
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (30) : 7294 - 7307
[30] LIGAND EFFECTS ON OXIDATIVE ADDITION REACTIONS OF D8 METAL COMPLEXES - PREPARATION AND OXIDATIVE ADDITION REACTIONS OF COMPLEXES OF TYPE TRANS- RH(CO)L2CL! (L=S(C2H5)2,SE(C2H5)2,TE(C2H5)2)
FARAONE, F
PIETROPA.R
SERGI, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 24 (03) : 797 - &

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