SYNTHESIS AND POLYMERIZATION OF N-[4-(CHOLESTEROXYCARBONYL)PHENYL]MALEIMIDE

被引：23

作者：

OISHI, T

OTSUBO, Y

MATSUSAKI, K

FUJIMOTO, M

机构：

[1] Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Yamaguchi University, Ube, Yamaguchi, 755

来源：

POLYMER | 1993年 / 34卷 / 07期

关键词：

POLYMERIZATION; N-[4-(CHOLESTEROXYCARBONYL)PHENYL]MALEIMIDE; OPTICALLY ACTIVE POLYMER; MONOMER REACTIVITY RATIO; Q; E VALUES; ASYMMETRIC INDUCTION COPOLYMERIZATION);

D O I：

10.1016/0032-3861(93)90869-C

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new type of optically active N-[4-(cholesteroxycarbonyl)phenyl]maleimide (ChPMI) was synthesized from maleic anhydride, aminobenzoic acid and cholesterol. Radical homopolymerizations of ChPMI were performed in several solvents at 70-degrees-C to give optically active polymers having [alpha]D = 2.3 to 41.1-degrees. Radical copolymerizations of ChPMI (M1) were performed with styrene (ST, M2) and methyl methacrylate (MMA, M2) in toluene at 70-degrees-C. From the results, the monomer reactivity ratios (r1, r2) and the Alfrey-Price Q, e values were determined as follows: r1 = 0.080, r2 = 0.020, Q1 = 6.57, e1 = 1.74 for the ChPMI-ST system; r1 = 0.11, r2 = 0.80, Q1 = 1.73, e1 = 1.96 for the ChPMI-MMA system. Anionic homopolymerizations of ChPMI were also carried out. Chiroptical properties of the polymers and copolymers were investigated.

引用

页码：1504 / 1511

页数：8

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