STEREOSELECTIVE [2,3]-SIGMATROPIC REARRANGEMENT OF CHIRAL AMINE OXIDES DERIVED FROM AMINO-ACIDS

被引：22

作者：

REETZ, MT

LAUTERBACH, EH

机构：

[1] Fachbereich Chemie der Universitaet, 3550 Marburg, Hans-Meerwein-Strasse

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 35期

关键词：

AMINO ACIDS; AMINE OXIDES; 2,3]-SIGMATROPIC REARRANGEMENT; DIASTEREOSELECTIVITY;

D O I：

10.1016/0040-4039(91)80017-Z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral gamma-N,N-dibenzylamino alpha,beta-unsaturated esters 1 are oxidized by m-chloro perbenzoic acid to form the amine oxides 2 which undergo a [2,3]-sigmatropic rearrangement with complete 1,3-transfer of chirality.

引用

页码：4481 / 4482

页数：2

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