OBSERVATION AND CHARACTERIZATION OF EXCIMER EMISSION FROM ANTHRACENE INCLUDED IN NAX ZEOLITE

被引:41
作者
HASHIMOTO, S [1 ]
FUKAZAWA, N [1 ]
FUKUMURA, H [1 ]
MASUHARA, H [1 ]
机构
[1] OSAKA UNIV,DEPT APPL PHYS,SUITA,OSAKA 565,JAPAN
关键词
D O I
10.1016/0009-2614(94)00114-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We observed for the first time an excimer emission of anthracene included in the supercages of zeolite X at high ratios of anthracene to supercage. The mechanism giving rise to the excimer emission was ascribed to charge recombination of anthracene cation-anion radical pairs on the basis of picosecond time-resolved diffuse reflectance transient absorption studies as well as picosecond fluorescence measurements.
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页码:445 / 451
页数:7
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