ON THE CALCULATION OF POINT-DEFECT EQUILIBRIA

被引：15

作者：

SPINOLO, G ^{[1
]}

ANSELMITAMBURINI, U ^{[1
]}

机构：

[1] UNIV PAVIA,CNR,CSTE,I-27100 PAVIA,ITALY

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1995年 / 99卷 / 01期

关键词：

POINT DEFECTS; THERMODYNAMICS;

D O I：

10.1002/bbpc.19950990115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A method is outlined for solving the equations describing the quasi chemical equilibria of point defects, with particular reference to binary oxides. The method gives exact solutions for all defect concentrations and the oxygen activity as a function of n = [e']. In comparison to the traditional approach, the feasibility of the method does not depend on the number of differently charged defects of the same kind. Possible extensions of the approach are briefly discussed.

引用

页码：87 / 90

页数：4