CATALYTIC HYDROCRACKING REACTION OF NASCENT COAL VOLATILE MATTER UNDER HIGH-PRESSURE

被引:22
作者
CHAREONPANICH, M
TAKEDA, T
YAMASHITA, H
TOMITA, A
机构
[1] Institute for Chemical Reaction Science, Tohoku University, Sendai, 980, Katahira
关键词
COAL PYROLYSIS; CATALYTIC HYDROCRACKING; SECONDARY REACTION;
D O I
10.1016/0016-2361(94)90006-X
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The volatile matter evolved during the rapid pyrolysis of coal was hydrocracked over catalysts in the last stage to increase the yield of valuable products like benzene, toluene and xylenes (BTX). The effects of gas atmosphere, coal type, pyrolysis temperature, hydrocracking temperature and catalyst type were examined. The highest BTX yield, 10.4 wt%(daf), was obtained under the following conditions: Millmerran coat, H-2 pressure of 5 MPa, primary pyrolysis temperature of 800-degrees-C, secondary hydrocracking temperature of 620-degrees-C and with a Ni-Mo-S catalyst.
引用
收藏
页码:666 / 670
页数:5
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