FULLERENE C-70, TOLUENE 1-1 SOLVATE - STRUCTURAL AND THERMODYNAMIC EVIDENCES

被引：19

作者：

AGAFONOV, V

CEOLIN, R

ANDRE, D

DEBRUIJN, J

GONTHIERVASSAL, A

SZWARC, H

RODIER, N

DUGUE, J

TOSCANI, S

SIZARET, PY

FABRE, C

GREUGNY, V

RASSAT, A

机构：

[1] UNIV PARIS 11,CNRS,CHIM PHYS MAT AMORPHES LAB,URA D1104,F-91405 ORSAY,FRANCE

[2] FAC PHARM CHATENAY MALABRY,CRISTALLOG LAB,F-92296 CHATENAY MALABRY,FRANCE

[3] FAC PHARM PARIS,CHIM MINERALE & STRUCT LAB,F-75270 PARIS 06,FRANCE

[4] FAC MED TOURS,UNITE MICROSCOPIE ELECTR,F-37042 TOURS,FRANCE

[5] ECOLE NORMALE SUPER,CNRS,URA 1110,ACTIVAT MOLEC LAB,F-75231 PARIS,FRANCE

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 208卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(93)80078-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray diffraction and thermodynamic measurements show that crystalline fullerene C70 obtained from toluene solutions is a C70, toluene 1: 1 solvate. Its structure is orthorhombic with space group Pbca (a= 21.075 angstrom, b= 32.990 angstrom, c= 10.844 angstrom). The evolution of this solvate towards the face-centered cubic and hexagonal phases of pure C70 is described and a hierarchy of relative stabilities of these latter phases is tentatively proposed.

引用

页码：68 / 72

页数：5

共 12 条

[1] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[2] TOLUENE - CRYSTAL AND MOLECULAR-STRUCTURE OF ALPHA-FORM AND AMORPHOUS MODIFICATION [J].

ANDERSON, M ;

BOSIO, L ;

BRUNEAUXPOULLE, J ;

FOURME, R .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1977, 74 (01) :68-73

[3] CRYSTAL-STRUCTURE OF THE METASTABLE BETA-PHASE OF TOLUENE [J].

ANDRE, D ;

FOURME, R ;

BRUNEAUXPOULLE, J ;

BOSIO, L .

JOURNAL OF MOLECULAR STRUCTURE, 1982, 81 (3-4) :253-259

[4] INTERCALATION OF MOLECULAR-SPECIES INTO THE INTERSTITIAL SITES OF FULLERENE [J].

ASSINK, RA ;

SCHIRBER, JE ;

LOY, DA ;

MOROSIN, B ;

CARLSON, GA .

JOURNAL OF MATERIALS RESEARCH, 1992, 7 (08) :2136-2143

[5] SOLID C-70 - A MOLECULAR-DYNAMICS STUDY OF THE STRUCTURE AND ORIENTATIONAL ORDERING [J].

CHENG, AL ;

KLEIN, ML .

PHYSICAL REVIEW B, 1992, 46 (08) :4958-4962

[6] PSEUDOTENFOLD SYMMETRY IN PENTANE-SOLVATED C60 AND C70 [J].

FLEMING, RM ;

KORTAN, AR ;

HESSEN, B ;

SIEGRIST, T ;

THIEL, FA ;

MARSH, P ;

HADDON, RC ;

TYCKO, R ;

DABBAGH, G ;

KAPLAN, ML ;

MUJSCE, AM .

PHYSICAL REVIEW B, 1991, 44 (02) :888-891

[7]

GRIVEI E, IN PRESS PHYS REV LE

[8] EFFICIENT PRODUCTION OF C60 (BUCKMINSTERFULLERENE), C60H36, AND THE SOLVATED BUCKIDE ION [J].

HAUFLER, RE ;

CONCEICAO, J ;

CHIBANTE, LPF ;

CHAI, Y ;

BYRNE, NE ;

FLANAGAN, S ;

HALEY, MM ;

OBRIEN, SC ;

PAN, C ;

XIAO, Z ;

BILLUPS, WE ;

CIUFOLINI, MA ;

HAUGE, RH ;

MARGRAVE, JL ;

WILSON, LJ ;

CURL, RF ;

SMALLEY, RE .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) :8634-8636

[9] ANALYSIS OF THE REORIENTATIONAL MOTION OF C-60 IN TOLUENE-D8 AT 303-K [J].

JONES, VK ;

RODRIGUEZ, AA .

CHEMICAL PHYSICS LETTERS, 1992, 198 (3-4) :373-378

[10] ORIENTATIONAL ORDERING IN SOLID C70 UNDER HIGH-PRESSURE [J].

KAWAMURA, H ;

KOBAYASHI, M ;

AKAHAMA, Y ;

SHINOHARA, H ;

SATO, H ;

SAITO, Y .

SOLID STATE COMMUNICATIONS, 1992, 83 (08) :563-565

← 1 2 →