KINETICS OF THE NUCLEOPHILIC-SUBSTITUTION REACTIONS IN THE SERIES OF POLYFLUOROAROMATIC COMPOUNDS

被引：0

作者：

RODIONOV, PP ^{[1
]}

FURIN, GG ^{[1
]}

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK,USSR

来源：

IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK | 1990年 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This treatment reviews the experimental data on the kinetics of nucleophilic substitution reactions in the series of polyfluoroaromatic compounds. The reviews discusses the effects of substituent, solvent, and nucleophilic reagent on the rate and orientation of the aromatic nucleophilic substitution, and the additivity problems of the ring fluorine effect on the reactivity of a substrate. The data are discussed on the reactivity of various polyfluoroaromatic compounds, including mono- and bicyclic ones, and of nitrogen-containing heterocyclic compounds.

引用

收藏

页码：3 / 26

页数：24

相关论文

共 88 条

[21] AROMATIC POLYFLUORO COMPOUNDS .34. NUCLEOPHILIC REPLACEMENT REACTIONS OF SOME TETRAFLUOROHALOGENOBENZENES [J].

BURDON, J ;

KING, DR ;

TATLOW, JC .

TETRAHEDRON, 1966, 22 (08) :2541-&

[22] KINETICS OF NUCLEOPHILIC SUBSTITUTION IN POLYFLUORO-AROMATIC COMPOUNDS .I. REACTION OF SODIUM METHOXIDE WITH SOME PENTAFLUOROPHENYL-COMPOUNDS [J].

BURDON, J ;

HOLLYHEAD, WB ;

PATRICK, CR ;

WILSON, KV .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (NOV) :6375-+

[23] A RATIONALIZATION OF ORIENTATION AND REACTIVITY IN NUCLEOPHILIC REPLACEMENT REACTIONS OF AROMATIC POLYHALO-COMPOUNDS [J].

BURDON, J .

TETRAHEDRON, 1965, 21 (12) :3373-&

[24] THE ELECTRONIC EFFECT OF THE PHENYLAZO AND TERT-BUTYLAZO GROUPS [J].

BYRNE, CJ ;

HAPPER, DAR ;

HARTSHORN, MP ;

POWELL, HKJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (11) :1649-1653

[25] NUCLEOPHILIC AROMATIC-SUBSTITUTION - KINETICS OF F-18 SUBSTITUTION-REACTIONS IN POLYFLUOROBENZENES - ISOTOPIC EXCHANGE BETWEEN F-18(-) AND POLYFLUOROBENZENES IN DIMETHYLSULFOXIDE [J].

CACACE, F ;

SPERANZA, M ;

WOLF, AP ;

MACGREGOR, RR .

JOURNAL OF FLUORINE CHEMISTRY, 1982, 21 (02) :145-158

[26]

CAHMBERS RD, 1988, J CHEM SOC P1, P255

[27] FLUORINATED HETEROCYCLIC-COMPOUNDS [J].

CHAMBERS, RD .

DYES AND PIGMENTS, 1982, 3 (2-3) :183-190

[28] MECHANISMS FOR REACTIONS OF HALOGENATED COMPOUNDS .1. ACTIVATING EFFECTS OF FLUORINE IN POLYFLUOROPYRIDINES IN REACTIONS WITH AMMONIA [J].

CHAMBERS, RD ;

WATERHOUSE, JS ;

WILLIAMS, DLH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (05) :585-588

[29] MECHANISMS FOR REACTIONS OF HALOGENATED COMPOUNDS .2. ORIENTING EFFECTS OF CHLORINE SUBSTITUENTS IN NUCLEOPHILIC AROMATIC-SUBSTITUTION [J].

CHAMBERS, RD ;

CLOSE, D ;

MUSGRAVE, WKR ;

WATERHOUSE, JS ;

WILLIAMS, DLH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1977, (13) :1774-1778

[30] MECHANISMS FOR REACTIONS OF HALOGENATED COMPOUNDS .4. ACTIVATING INFLUENCES OF RING-NITROGEN AND TRIFLUOROMETHYL IN NUCLEOPHILIC AROMATIC-SUBSTITUTION [J].

CHAMBERS, RD ;

MARTIN, PA ;

WATERHOUSE, JS ;

WILLIAMS, DLH ;

ANDERSON, B .

JOURNAL OF FLUORINE CHEMISTRY, 1982, 20 (04) :507-514

← 1 2 3 4 5 6 7 8 9 →