THE EFFECT OF THE PH DIFFERENCE BETWEEN PHASES ON PARTITIONING IN POLY(ETHYLENE GLYCOL)-PHOSPHATE AQUEOUS 2-PHASE SYSTEMS

被引:14
|
作者
EITEMAN, MA [1 ]
GAINER, JL [1 ]
机构
[1] UNIV VIRGINIA,CTR BIOPROC & PROD DEV,DEPT CHEM ENGN,THORNTON HALL,CHARLOTTESVILLE,VA 22903
基金
美国国家科学基金会;
关键词
POLY(ETHYLENE) GLYCOL; 2-PHASE SYSTEMS; PARTITION COEFFICIENT; PH; SEPARATIONS; CHARGE EFFECTS;
D O I
10.1080/00986449108911524
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The pH difference existing between phases of poly(ethylene glycol)-potassium phosphate aqueous two-phase systems is shown to affect the partition coefficients of charged solutes. This effect is modeled and experimental results agree with the behavior predicted. © 1991, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码:171 / 183
页数:13
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