ION-IMPLANTATION INTO POLYETHYLENE

被引：17

作者：

SVORCIK, V ^{[1
]}

RYBKA, V ^{[1
]}

ENDRST, R ^{[1
]}

HNATOWICZ, V ^{[1
]}

KVITEK, J ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI, INST NUCL PHYS, CS-25068 REZ, CZECHOSLOVAKIA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1993年 / 140卷 / 02期

关键词：

Conductive plastics - Degradation - Electric conductivity - Fluorine containing polymers - Ion implantation;

D O I：

10.1149/1.2221084

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The polyethylene samples implanted with F+ ions at different implantation energies and to the ion fluences from 10(11)-10(15) cm-2 were studied by means of IR and UV-visible spectroscopies, by the standard Rutherford backscattering method and the measurement of surface energy. It was found that the fluorine atoms are not bound in the polymer. As a result of the F+ ion implantation, the carbonyl groups and conjugated double bonds are created on the polymer chain. The surface polarity of implanted polyethylene samples increases with increasing ion fluence. The degree of the polyethylene degradation is an increasing function of the implantation energy. By the implantation with F+ ions to the fluence of 10(15) cm-2, the polyethylene electrical conductivity was increased by six to seven orders of magnitude compared to that of pristine polymer.

引用

页码：542 / 544

页数：3

共 9 条

[1] IODINE IMPLANTATION OF POLYMERIC PHTHALOCYANINES [J].

DANN, AJ ;

FAHY, MR ;

JEYNES, C ;

WILLIS, MR .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1986, 19 (11) :L217-L224

[2]

Dolezel B., 1978, BESTANDIGKEIT KUNSTS

[3]

Guang-hou W, 1987, NUCL INSTRUM METH B, V27, P410

[4] CONDUCTING POLYMERS BY ION-IMPLANTATION [J].

LOH, IH ;

OLIVER, RW ;

SIOSHANSI, P .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1988, 34 (03) :337-346

[5]

Ranby B. G., 1975, PHOTODEGRADATION PHO

[6] ION-IMPLANTATION ENHANCED ADHESION OF POLYPROPYLENE [J].

SVORCIK, V ;

RYBKA, V ;

SEIDL, P ;

HNATOWICZ, V ;

KVITEK, J ;

GERYK, K .

MATERIALS LETTERS, 1992, 12 (06) :434-436

[7]

SVORCIK V, 1992, JPN J APPL PHYS PT 2, V31, P291

[8]

SVORCIK V, IN PRESS J APPL POLY

[9] STRUCTURE AND MORPHOLOGY OF ION-IMPLANTED POLYIMIDE FILMS [J].

YOSHIDA, K ;

IWAKI, M .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1987, 19-20 :878-881

← 1 →