STRUCTURAL-ANALYSIS OF SULFUR IN RUBBER BY X-RAY NEAR EDGE ABSORPTION-SPECTROSCOPY (XANES)

被引：0
作者：
CHAUVISTRE, R
HORMES, J
BRUCK, D
SOMMER, K
ENGELS, HW
机构：
[1] UNIV BONN,INST PHYS,W-5300 BONN,GERMANY
[2] BAYER AG,RUBBER BUSINESS GRP,W-5090 LEVERKUSEN,GERMANY
[3] BAYER AG,POLYMER PHYS GRP,CENT RES,W-5090 LEVERKUSEN,GERMANY
来源：
KAUTSCHUK GUMMI KUNSTSTOFFE | 1992年 / 45卷 / 10期
关键词：
VULCANIZATE; SULFUR CROSS-LINKS; NETWORK STRUCTURE; X-RAY NEAR EDGE ABSORPTION SPECTROSCOPY; XANES;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The authors would like to introduce X-ray near edge absorption spectroscopy (XANES) as a new tool in sulfur crosslink analysis. As compared to other techniques XANES has some important advantages. Recent studies have shown the good sensitivity of K shell XANES-spectra to the local geometric and electronic environment of sulfur. Various applications of XANES-spectroscopy in the field of structural analysis of sulfur components are demonstrated. Time dependent changes in a vulcanizate could be monitored.
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页码：808 / 813
页数：6
相关论文
共 18 条
[1]   ANGULAR-DEPENDENCE OF X-RAY ABSORPTION-SPECTRA [J].
BROUDER, C .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1990, 2 (03) :701-738
[2]   HIGH-RESOLUTION SYNCHROTRON SPECTROSCOPY WITH AND WITHOUT MAGNETIC-FIELDS [J].
CONNERADE, JP ;
HORMES, J .
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1986, 4 (01) :3-14
[3]  
GRONSKI W, 1991, KAUT GUMMI KUNSTST, V44, P119
[4]   INNER SHELL EXCITATION OF THIOPHENE AND THIOLANE - GAS, SOLID, AND MONOLAYER STATES [J].
HITCHCOCK, AP ;
HORSLEY, JA ;
STOHR, J .
JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (09) :4835-4848
[5]   SULFUR AND CHLORINE K-SHELL X-RAY ABSORPTION-SPECTRA OF SCL2, S2CL2, SOCL2 AND SO2CL2 [J].
HITCHCOCK, AP ;
BODEUR, S ;
TRONC, M .
CHEMICAL PHYSICS, 1987, 115 (01) :93-101
[6]   SULFUR AND CHLORINE K-SHELL SPECTRA OF GASES [J].
HITCHCOCK, AP ;
BODEUR, S ;
TRONC, M .
PHYSICA B, 1989, 158 (1-3) :257-258
[7]  
HITCHCOCK AP, 1986, J PHYSIQUE, P575
[8]  
KEMPERMANN T, 1981, KAUT GUMMI KUNSTST, V34, P722
[9]  
Koch E.-E., 1983, HDB SYNCHROTRON RAD
[10]  
Konigsberger D., 1988, CHEM ANAL, V92
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