A NOVEL RECEPTOR FOR DICARBOXYLIC-ACID DERIVATIVES

被引：49
作者：
FLACK, SS [1 ]
CHAUMETTE, JL [1 ]
KILBURN, JD [1 ]
LANGLEY, GJ [1 ]
WEBSTER, M [1 ]
机构：
[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期
关键词：
D O I：
10.1039/c39930000399
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel receptor 4 has been prepared, which binds the monopotassium salts of various dicarboxylic acids in chloroform solution, using a combination of hydrogen bonding interactions and an electrostatic association between a carboxylate anion and a crown ether bound potassium cation, the crystal structure of the receptor is reported and evidence for the proposed binding interactions is provided by consideration of various extraction experiments, intermolecular NOEs (nuclear Overhausser effect), and FAB (fast atom bombardment) mass spectrometry, where a bimolecular species, held together by hydrogen bonds, can be detected in the negative ion mass spectrum.
引用
收藏
页码：399 / 401
页数：3
相关论文
共 50 条
  • [31] REACTION OF ACETONE OXIME WITH DICARBOXYLIC-ACID CHLORIDES
    IZYDORE, RA
    DAVIS, RG
    CLEMENTS, NW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1982, 183 (MAR): : 174 - ORGN
  • [32] SYNTHESIS OF DICARBOXYLIC-ACID FUNCTIONALIZED POLYSILOXANE MACROMERS
    KAWAKAMI, Y
    SAIBARA, S
    SUZUKI, F
    ABE, T
    YAMASHITA, Y
    POLYMER BULLETIN, 1991, 25 (05) : 521 - 527
  • [33] ACYLATION OF DIMEDON ENAMINES BY DICARBOXYLIC-ACID ANHYDRIDES
    AGBALYAN, SG
    NSHANYAN, AO
    ARMYANSKII KHIMICHESKII ZHURNAL, 1972, 25 (11): : 981 - 982
  • [34] GELATION IN REACTIONS OF DICARBOXYLIC-ACID DICHLORIDES WITH TRIOLS
    SMITH, RS
    STEPTO, RFT
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1974, 175 (08): : 2365 - 2373
  • [35] SYNTHESIS AND COMPLEX-FORMING PROPERTIES OF COMPLEXONS AS DICARBOXYLIC-ACID DERIVATIVES .4. IMINODISUCCINIC ACID
    MALAKHAEV, ED
    NIKOLSKII, VM
    GORELOV, IP
    ZHURNAL OBSHCHEI KHIMII, 1978, 48 (11): : 2601 - 2604
  • [36] CHIRAL MOLECULAR CLEFTS FOR DICARBOXYLIC-ACID COMPLEXATION
    ALCAZAR, V
    MORAN, JR
    DIEDERICH, F
    ISRAEL JOURNAL OF CHEMISTRY, 1992, 32 (01) : 69 - 77
  • [37] DICARBOXYLIC-ACID DIPEPTIDE NEUTRAL ENDOPEPTIDASE INHIBITORS
    KSANDER, GM
    GHAI, RD
    DEJESUS, R
    DIEFENBACHER, CG
    YUAN, A
    BERRY, C
    SAKANE, Y
    TRAPANI, A
    JOURNAL OF MEDICINAL CHEMISTRY, 1995, 38 (10) : 1689 - 1700
  • [38] REACTIONS OF ORGANOSILICON PEROXIDES WITH DICARBOXYLIC-ACID ANHYDRIDES
    RAZUVAEV, GA
    BASOVA, GV
    DODONOV, VA
    DYACHKOVSKAYA, OS
    AN, AK
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (01): : 157 - 160
  • [39] FUNCTIONALITY OF OLIGOESTERS ON BASIS OF XYLITOL AND DICARBOXYLIC-ACID
    BAZHENOVA, TA
    GRACHEVA, LI
    SHOSHTAEVA, MV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1977, 19 (02): : 376 - 380
  • [40] INTERACTION OF VANADIUM(V) WITH THE DICARBOXYLIC-ACID COMPLEXONES
    PECHUROVA, NI
    TRUBACHIOVA, LA
    BREZHNEVA, MA
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1984, 25 (01): : 64 - 68
12345