CATIONIC OLIGOMERIZATION OF ISOPRENE AND STRUCTURE OF ITS OLIGOMERS

被引：4

作者：

AUDISIO, G

PRIOLA, A

ROSSINI, A

机构：

[1] POLITECN TORINO, DIPARTIMENTO SCI MAT & INGN CHIM, CORSO DUCA DEGLI ABRUZZI 24, I-10129 TURIN, ITALY

[2] CNR, IST CHIM MACROMOLEC, I-20133 MILAN, ITALY

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1991年 / 47卷

关键词：

D O I：

10.1002/masy.19910470121

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The results obtained in a study of isoprene cationic oligomerization in the presence of some oxyacids (H2SO4, CH3SO3H, Nafion(R) H) are reported. Oligomers up to pentamers are obtained which were examined through gas chromatography/mass spectrometry analysis either of the reaction products or of the hydrogenated products. The structure of the dimer fraction was investigated and revealed the prevalent presence of alpha-pinene and p-cymene together with different cyclic unsaturated hydrocarbons. Only small quantities of linear dimers were found. Possible reaction mechanisms are presented.

引用

页码：263 / 270

页数：8