OXIDATION OF OLEFINS WITH ALKANESULFOPERACIDS

被引：3
|
作者：
SAFIULLIN, RL
ENIKEEVA, LR
SERENKO, SY
KOMISSAROV, VD
TOLSTIKOV, GA
机构：
[1] Institute of Chemistry, Bashkir Science Center, Ural Branch, Academy of Sciences, of the USSR, Ufa
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 02期
关键词：
D O I：
10.1007/BF00965415
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alkanesulfonic peracids RSO4H effectively oxidize olefins to the corresponding epoxides. The kinetics and mechanism of this reaction are studied. It was shown that both the monomer and dimer form of the peracid act as oxidizing agents. The dependence of the weight constant of the reaction of monomer RSO4H with substituted acyclic olefins on the structure of the latter is described by the Taft equation. A linear correlation is established between log k2 and the inductive constants of the substituents on the oxygen atom in the peracid.
引用
收藏
页码：280 / 284
页数：5
相关论文
共 50 条
  • [41] MECHANISM OF NITRIC ACID OXIDATION OF OLEFINS
    FRANZ, JE
    HERBER, JF
    KNOWLES, WS
    JOURNAL OF ORGANIC CHEMISTRY, 1965, 30 (05) : 1488 - &
  • [42] Advances in Electrochemical Oxidation of Olefins to Epoxides
    Zhang, Peng
    Wang, Tuo
    Gong, Jinlong
    CCS CHEMISTRY, 2023, 5 (05): : 1028 - 1042
  • [43] SULFUR OXIDATION OF OLEFINS TO KETONES - PETR
    SUZUKI, S
    RANSLEY, DL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1970, (FEB): : 76 - &
  • [44] OXIDATION OF OLEFINS TO KETONES IN COMBINATION WITH ELECTROOXIDATION
    TSUJI, J
    MINATO, M
    TETRAHEDRON LETTERS, 1987, 28 (32) : 3683 - 3686
  • [45] MECHANISM OF SELENIUM DIOXIDE OXIDATION OF OLEFINS
    TRACHTENBERG, EN
    NELSON, CH
    CARVER, JR
    JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (05) : 1653 - +
  • [46] OXIDATION OF OLEFINS WITH PALLADIUM CHLORIDE CATALYSTS
    SMIDT, J
    CHEMISTRY & INDUSTRY, 1962, (02) : 54 - 61
  • [47] MECHANISM OF NITRIC ACID OXIDATION OF OLEFINS
    FRANZ, JE
    KNOWLES, WS
    CHEMISTRY & INDUSTRY, 1961, (08) : 250 - 251
  • [48] OXIDATION OF OLEFINS BY SUPPORTED CHROMIUM OXIDE
    BAKER, LM
    CARRICK, WL
    JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (02) : 616 - &
  • [49] CHROMIC-ACID OXIDATION OF NITRO-OLEFINS AND BROMONITRO-OLEFINS
    SHAFIULLAH
    SHAMSUZZAMAN
    ANSARI, JA
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1988, 27 (07): : 676 - 677
  • [50] A NEW REACTION IN SELENIUM DIOXIDE OXIDATION OF OLEFINS
    JAVAID, KA
    SONODA, N
    TSUTSUMI, S
    TETRAHEDRON LETTERS, 1969, (51) : 4439 - &
12345