SECONDARY MOLD METABOLITES .13. FUNGAL PERYLENEQUINONES - PHLEICHROME, ISOPHLEICHROME, AND THEIR ENDOPEROXIDES

被引：35

作者：

ARNONE, A ^{[1
]}

CAMARDA, L ^{[1
]}

NASINI, G ^{[1
]}

MERLINI, L ^{[1
]}

机构：

[1] UNIV MILAN, FAC AGR, IST BIOCHIM GEN, I-20133 MILAN, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1985年 / 07期

关键词：

D O I：

10.1039/p19850001387

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The helix-shaped, fungal [Cladosporium phlei] pigment phleichrome has been isomerized to isophleichrome. The axial chirality and absolute configuration of the side-chain carbons of both perylenequinones have been established. Photo-oxidation of both compounds occurs stereospecifically to give their endoperoxides, whose structure and stereochemistry results from a detailed analysis of their n.m.r. spectra.

引用

页码：1387 / 1392

页数：6

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