AN UNPRECEDENTED PALLADIUM-CATALYZED CARBON METAL BOND FORMATION

被引：1

作者：

STERZO, CL

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 12期

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D O I：

10.1039/dt9920001989

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Fe(eta-5-C5H4R)(CO)2I] (R = styryl) with [Mn(eta-5-C5H4C=CSnMe3)(CO)3] in dimethyl-formamide in the presence of catalytic amounts (5%) of [PdCl2(MeCN)2] produces [(OC)2(eta-5-RC5H4) Fe-C=C-(eta-4-C5H4)Mn(CO)3] in good yield; the crystal structure of the tetrahedral pyramidal adduct formed by reaction of this coupled product with [Co2(CO)8] has been determined.

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页码：1989 / 1990

页数：2

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